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Курсовая работа: Энтальпия образования индивидуальных веществ. Прогнозирование энтальпии образования методом Бенсона
Продолжение табл. 1.2
Группа |
кДж/моль
|
, Дж/(моль×К)
|
, Дж/(моль×К) при температуре, К
|
298 |
400 |
500 |
600 |
800 |
1000 |
1500 |
NH–(2CO) |
-77,44 |
31,81 |
15,03 |
23,19 |
28,05 |
30,93 |
33,28 |
34,28 |
|
NH–(2C) |
64,46 |
37,42 |
17,58 |
21,81 |
25,66 |
28,59 |
33,07 |
36,21 |
39,97 |
NH–(Cb,CO) |
1,67 |
-12,14 |
2,39 |
6,32 |
9,96 |
13,94 |
16,91 |
18,21 |
|
NH–(Cb,N) |
92,51 |
47,72 |
|
|
|
|
|
|
|
NH–(C,Cb) |
62,37 |
28,46 |
15,99 |
20,47 |
23,9 |
26,29 |
30,1 |
32,36 |
|
NH–(C,CO) |
-18,42 |
16,32 |
2,76 |
6,49 |
10,3 |
14,57 |
17,75 |
18,96 |
|
NH–(C,N) |
87,48 |
40,18 |
20,09 |
24,28 |
27,21 |
29,3 |
32,65 |
34,74 |
37,67 |
NH–(C,=C) |
64,46 |
|
|
|
|
|
|
|
|
NH–(C,=Nim) |
87,9 |
|
|
|
|
|
|
|
|
NH–(=C,N) |
90 |
|
|
|
|
|
|
|
|
NH2–(Cb)
|
20,09 |
124,36 |
23,94 |
27,25 |
30,64 |
33,78 |
39,39 |
43,83 |
51,4 |
NH2–(CO)
|
-62,37 |
103,35 |
17,04 |
24,03 |
29,85 |
34,7 |
41,69 |
46,97 |
|
NH2–(C)
|
20,09 |
124,36 |
23,94 |
27,25 |
30,64 |
33,78 |
39,39 |
43,83 |
51,4 |
NH2–(N)
|
47,72 |
121,81 |
25,53 |
30,98 |
35,16 |
38,93 |
43,95 |
48,14 |
55,25 |
NH2–(=C)
|
20,09 |
|
|
|
|
|
|
|
|
NH2–(=Nim)
|
47,72 |
|
|
|
|
|
|
|
|
N(NO2)–(2C)
|
50,23 |
|
|
|
|
|
|
|
|
=Naz–(Cb) |
132,69 |
|
|
|
|
|
|
|
|
=Naz–(C) |
113,02 |
35,58 |
11,3 |
17,16 |
20,59 |
22,35 |
23,82 |
23,9 |
|
=Naz–(N) |
96,27 |
35,58 |
8,87 |
17,5 |
23,06 |
28,34 |
28,71 |
29,51 |
|
=NazH |
105,06 |
112,18 |
18,33 |
20,47 |
22,77 |
24,86 |
28,34 |
31,06 |
35,33 |
=Nim–(Cb) |
65,3 |
25,12 |
12,56 |
|
|
|
|
|
|
=Nim–(C) |
89,16 |
24,7 |
10,38 |
13,98 |
16,53 |
17,96 |
19,21 |
19,25 |
|
=Nim–(N) |
104,23 |
|
|
|
|
|
|
|
|
=NimH |
50,23 |
51,49 |
12,35 |
19,17 |
27 |
32,27 |
38,22 |
41,52 |
|
Серосодержащие группы
|
S–(2Cb) |
108,41 |
-113,02 |
8,37 |
8,41 |
9,38 |
11,47 |
15,91 |
19,72 |
|
S–(2C) |
48,18 |
55,04 |
20,89 |
20,76 |
21,01 |
21,22 |
22,65 |
23,98 |
|
S–(2O) |
37,67 |
|
|
|
|
|
|
|
|
S–(2S) |
13,39 |
56,09 |
19,67 |
20,93 |
21,35 |
21,77 |
22,19 |
22,6 |
|
S–(2=C) |
-19 |
68,98 |
20,05 |
23,36 |
23,15 |
26,33 |
33,24 |
40,73 |
|
S–(Cb,B) |
-32,65 |
|
|
|
|
|
|
|
|
S–(Cb,S) |
60,69 |
-33,49 |
12,1 |
14,19 |
15,57 |
17,37 |
20,01 |
21,35 |
|
S–(C,B) |
-60,69 |
|
|
|
|
|
|
|
|
S–(C,Cb) |
80,2 |
-32,65 |
12,64 |
14,19 |
15,53 |
16,91 |
19,34 |
20,93 |
|
S–(C,S) |
29,51 |
51,78 |
21,89 |
22,69 |
23,06 |
23,06 |
22,52 |
21,43 |
|
S–(C,=C) |
41,73 |
55,25 |
17,66 |
21,26 |
23,27 |
24,15 |
24,57 |
24,57 |
|
S–(N,S) |
-20,51 |
|
|
|
|
|
|
|
|
SH–(Cb) |
50,06 |
52,99 |
21,43 |
22,02 |
23,32 |
25,24 |
29,26 |
32,82 |
|
SH–(CO) |
-5,9 |
130,6 |
31,94 |
33,86 |
33,99 |
34,2 |
35,58 |
34,49 |
|
SH–(C) |
19,34 |
137 |
24,53 |
25,95 |
27,25 |
28,38 |
30,56 |
32,27 |
|
SH–(=C) |
25,53 |
|
|
|
|
|
|
|
|
SO–(2Cb) |
-66,97 |
-99,2 |
23,94 |
38,05 |
40,6 |
47,93 |
47,97 |
47,09 |
|
SO–(2C) |
-66,97 |
75,76 |
37,17 |
41,98 |
43,95 |
45,17 |
45,96 |
46,76 |
|
SO–(2N) |
-132,11 |
|
|
|
|
|
|
|
|
SO–(2O) |
-213,48 |
|
|
|
|
|
|
|
|
SO–(C,Cb) |
-72,04 |
-12,56 |
|
|
|
|
|
|
|
SO2–(2Cb)
|
-296,44 |
-72,42 |
34,99 |
46,17 |
56,72 |
62,54 |
66,39 |
66,81 |
|
SO2–(2C)
|
-288,82 |
87,48 |
48,22 |
50,1 |
55,88 |
59,77 |
64,38 |
66,47 |
|
SO2–(2N)
|
-132,11 |
|
|
|
|
|
|
|
|
Продолжение табл. 1.2
Группа |
кДж/моль
|
, Дж/(моль×К)
|
, Дж/(моль×К) при температуре, К
|
298 |
400 |
500 |
600 |
800 |
1000 |
1500 |
SO2–(2O)
|
-417,5 |
|
|
|
|
|
|
|
|
SO2–(2=С)
|
-308,08 |
56,51 |
48,22 |
50,1 |
55,88 |
59,77 |
64,38 |
66,47 |
|
SO2–(Сb,SO2)
|
-325,32 |
-13,39 |
41,06 |
48,14 |
56,59 |
61,66 |
65,76 |
67,1 |
|
SO2–(Сb,=C)
|
-296,44 |
-26,37 |
41,4 |
48,14 |
55,88 |
61,16 |
65,8 |
66,64 |
|
SO2–(С,Cb)
|
-289,24 |
5,86 |
41,61 |
48,14 |
56,3 |
60,74 |
65,38 |
66,64 |
|
SO2–(С,=C)
|
-316,95 |
75,76 |
|
|
|
|
|
|
|
SO3–(2С)
|
-396,82 |
126,83 |
|
|
|
|
|
|
|
SO4–(2С)
|
-602,34 |
138,55 |
|
|
|
|
|
|
|
S(CN)–(Сb) |
196,74 |
138,55 |
39,77 |
|
|
|
|
|
|
S(CN)–(С) |
175,81 |
181,67 |
46,88 |
|
|
|
|
|
|
S(CN)–(=С) |
198,83 |
196,74 |
59,44 |
|
|
|
|
|
|
(SO2Cl)–(O)
|
-406,03 |
|
|
|
|
|
|
|
|
(SO2F)–(O)
|
-594,39 |
|
|
|
|
|
|
|
|
Фосфорсодержащие группы
|
P–(3Сb) |
118,46 |
|
|
|
|
|
|
|
|
P–(3С) |
29,3 |
|
|
|
|
|
|
|
|
P–(3N) |
-279,61 |
|
|
|
|
|
|
|
|
P–(3O) |
-279,61 |
|
|
|
|
|
|
|
|
PCl2–(C)
|
-209,71 |
|
|
|
|
|
|
|
|
PO–(3Cb) |
-221,43 |
|
|
|
|
|
|
|
|
PO–(3C) |
-304,73 |
|
|
|
|
|
|
|
|
PO–(3N) |
-437,84 |
|
|
|
|
|
|
|
|
PO–(3O) |
-437,84 |
|
|
|
|
|
|
|
|
PO–(C,2O) |
-416,49 |
|
|
|
|
|
|
|
|
P=N–(2Cb,
N=P, P=N)
|
-95,86 |
|
|
|
|
|
|
|
|
P=N–(2C,
N=P, P=N)
|
-64,88 |
|
|
|
|
|
|
|
|
P=N–(2O,
N=P, P=N)
|
-181,67 |
|
|
|
|
|
|
|
|
P=N–(C,3Cb) |
-107,58 |
|
|
|
|
|
|
|
|
P=N–(C,3C) |
2,09 |
|
|
|
|
|
|
|
|
(PO)Cl–(C,O) |
-471,33 |
|
|
|
|
|
|
|
|
(PO)Cl2–(C)
|
-514,86 |
221,72 |
|
|
|
|
|
|
|
(PO)F–(2O) |
-701,97 |
|
|
|
|
|
|
|
|
(P=N)Cl2–(N=P,P=N)
|
-243,62 |
|
|
|
|
|
|
|
|
Группы,
содержащие атомы бора и кремния
|
B–(2C,O) |
122,65 |
|
|
|
|
|
|
|
|
B–(3C) |
3,73 |
|
|
|
|
|
|
|
|
B–(3N) |
102,13 |
|
|
|
|
|
|
|
|
B–(3O) |
102,13 |
|
|
|
|
|
|
|
|
B–(3S) |
102,13 |
|
|
|
|
|
|
|
|
B–(B,2O) |
-376,56 |
|
|
|
|
|
|
|
|
B–(C,N,O) |
-43,95 |
|
|
|
|
|
|
|
|
BBr–(2Cb) |
-239,64 |
|
|
|
|
|
|
|
|
BBr–(2C) |
-112,6 |
|
|
|
|
|
|
|
|
BBr2–(Cb)
|
-244,45 |
|
|
|
|
|
|
|
|
BCl–(2C) |
-178,74 |
|
|
|
|
|
|
|
|
Продолжение табл. 1.2
Группа |
кДж/моль
|
, Дж/(моль×К)
|
, Дж/(моль×К) при температуре, К
|
298 |
400 |
500 |
600 |
800 |
1000 |
1500 |
BCl–(2N) |
-83,05 |
|
|
|
|
|
|
|
|
BCl–(2O) |
-82,46 |
|
|
|
|
|
|
|
|
BCl2–(Cb)
|
-381,25 |
|
|
|
|
|
|
|
|
BCl2–(N)
|
-284,22 |
|
|
|
|
|
|
|
|
BCl2–(O)
|
-256,17 |
|
|
|
|
|
|
|
|
BF2–(C)
|
-786,52 |
|
|
|
|
|
|
|
|
B–(2C,O) |
122,65 |
|
|
|
|
|
|
|
|
B–(3C) |
3,73 |
|
|
|
|
|
|
|
|
B–(3N) |
102,13 |
|
|
|
|
|
|
|
|
B–(3O) |
102,13 |
|
|
|
|
|
|
|
|
B–(3S) |
102,13 |
|
|
|
|
|
|
|
|
B–(B,2O) |
-376,56 |
|
|
|
|
|
|
|
|
B–(C,N,O) |
-43,95 |
|
|
|
|
|
|
|
|
BBr–(2Cb) |
-239,64 |
|
|
|
|
|
|
|
|
BBr–(2C) |
-112,6 |
|
|
|
|
|
|
|
|
BBr2–(Cb)
|
-244,45 |
|
|
|
|
|
|
|
|
BCl–(2C) |
-178,74 |
|
|
|
|
|
|
|
|
BCl–(2N) |
-83,05 |
|
|
|
|
|
|
|
|
BCl–(2O) |
-82,46 |
|
|
|
|
|
|
|
|
BCl2–(Cb)
|
-381,25 |
|
|
|
|
|
|
|
|
BCl2–(N)
|
-284,22 |
|
|
|
|
|
|
|
|
BCl2–(O)
|
-256,17 |
|
|
|
|
|
|
|
|
BF2–(C)
|
-786,52 |
|
|
|
|
|
|
|
|
BF2–(=C)
|
-807,45 |
|
|
|
|
|
|
|
|
BH–(2O) |
83,3 |
|
|
|
|
|
|
|
|
BI–(2C) |
-37,25 |
|
|
|
|
|
|
|
|
BO3–(3C)
|
-873,59 |
|
|
|
|
|
|
|
|
Si–(2C,2Si) |
-19,88 |
|
|
|
|
|
|
|
|
Si–(3C,Si) |
-55,04 |
|
|
|
|
|
|
|
|
Si–(4Cb) |
-608,2 |
|
|
|
|
|
|
|
|
Si–(4C) |
-64,46 |
184,51 |
113,23 |
134,95 |
154,5 |
171,2 |
198,62 |
219,72 |
252,91 |
SiBr–(3C) |
-251,15 |
|
|
|
|
|
|
|
|
SiCl–(3C) |
-227,38 |
|
|
|
|
|
|
|
|
SiCl2–(2C)
|
-364,13 |
|
|
|
|
|
|
|
|
SiCl3–(C)
|
-529,85 |
|
|
|
|
|
|
|
|
SiH–(3C) |
-59,36 |
|
|
|
|
|
|
|
|
SiH2–(2C)
|
-88,15 |
|
|
|
|
|
|
|
|
SiH3–(C)
|
-8,37 |
129,13 |
-39,64 |
|
|
|
|
|
|
SiHCl–(2C) |
208,33 |
|
|
|
|
|
|
|
|
SiHCl2–(C)
|
-359,98 |
|
|
|
|
|
|
|
|
Металлсодержащие
группы
|
Al–(3C) |
38,51 |
|
|
|
|
|
|
|
|
AlH–(2C) |
-2,76 |
|
|
|
|
|
|
|
|
Cd–(2C) |
194,22 |
|
|
|
|
|
|
|
|
Cr–(4O) |
-267,89 |
|
|
|
|
|
|
|
|
Ge–(3Cb,Ge) |
124,24 |
|
|
|
|
|
|
|
|
Ge–(3C,Ge) |
26,41 |
|
|
|
|
|
|
|
|
Ge–(4Cb) |
86,4 |
|
|
|
|
|
|
|
|
Ge–(4C) |
98,03 |
|
|
|
|
|
|
|
|
Hg–(2Cb) |
269,57 |
|
|
|
|
|
|
|
|
Продолжение табл. 1.2
Страницы: 1, 2, 3, 4, 5, 6
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|